In Situ Electrochemical Investigations of Inherently Chiral 2,2′‐Biindole Architectures with Oligothiophene Terminals
نویسندگان
چکیده
Abstract The synthesis and characterization of three new inherently chiral N , N′ ‐dipropyl‐3,3′‐diheteroaryl‐2,2′‐biindole monomers, nicknamed Ind 2 T 4 6 Ph which differ in the number thiophenes as terminals, are reported. In addition to a full monomer characterization, stable electroactive oligomeric films were obtained by electro‐oxidation upon cycling potentials activate thiophene terminals. Cyclic voltammetry, UV‐Vis‐NIR spectroelectrochemistry situ conductance measurements show that present best stability electrochromic switching performance. Enantioselective tests with ferrocene amine clearly potential selectors for analytical sensing purposes.
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......................................................................................... i Acknowledgments ........................................................................ iii Publications and Presentations ..................................................... v Primary Research Papers .......................................................... v Other Research Papers .....................
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ژورنال
عنوان ژورنال: ChemElectroChem
سال: 2021
ISSN: ['2196-0216']
DOI: https://doi.org/10.1002/celc.202100511